Freemium is not a business model.  It is a marketing tactic, and can be used effectively for 3 primary purposes:  to build awareness and trial, to serve as a customer acquisition engine through referrals, or to help a business achieve a networked effect.  In addition, there are several risks to offering your product for free–most importantly, that you risk sending out a message that your product has no value worth paying for.  I recently talked with my friend Linda Popky, of Leverage2Market Associates about best and worst practices in Freemium.  If you'd like to listen, download the podcast.